As shipped, the shape is in a tight ball. How do I reshape it into a fluffy open shape as pictured?

I wish I had a good answer for you, but I have had ZERO luck reshaping this. It's packed tightly and nothing I've tried has fluffed it. :(

Will this head fit on a painting Pole

Yes, it will as long as the pole tip is standard threaded, and most painter's poles are.

What is the brush diameter? Are the bristles stiff enough to use to clean out a dryer duct vent?

The diameter is just under 5˝ so it will fit in the typical 4˝ dryer vent. The bristles are stiff enough, but they all point forward. This may work OK, but likely would make it difficult to pull the dirt back out of the vent. If your goal is to dislodge the material so it can be blown out, I think that would work.

Manufacturer	DOCAZOO
Model Number	DCZ-FGS-P038-01-AA1US
Package Dimensions	26.1 x 11.5 x 7.9 cm
Color	イエローとグレー(コブウェブダスター)。
Size	One Size (Attachment Only)
Special Features	伸縮ハンドル
Package Weight	0.21 Kilograms
Batteries Required	No
Batteries Included	No
Material Care Instructions	手洗いのみ
Brand Name	DOCAZOO
Item Weight	190 Grams

DOCAZOO DocaPole マイクロファイバーダスター、天井、コーナー、クモの巣ダスティングアタッチメント 高い天井や表面用 ホームクリーニングキット ポールは含まれません

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DOCAZOO DocaPole マイクロファイバーダスター、天井、コーナー、クモの巣ダスティングアタッチメント高い天井や表面用ホームクリーニングキットポールは含まれません